Carbazole monomer with a side chain nitroxyl radical 4-(9H-carbazol-9-yl)acetyl-oxy-2,2,6,6-tetramethylpiperidin-1-yloxy (Cz-TEMPO), was designed and synthesized successfully. The corresponding polymer electrode poly(carbazole-TEMPO) (PCz-TEMPO) has been electrochemically prepared in CH₃CN solution with different supporting electrolytes. PCz-TEMPO film was homogeneously dispersed on the surface of Pt electrode and characterized by FTIR, SEM, XPS and element mapping. The electrocatalytic performances of PCz-TEMPO electrode for oxidation of benzyl alcohol were investigated by cyclic voltammetry and in situ FTIR spectroscopy. Tetrabutylammonium tetrafluoroborate (TTFB) was the most efficient supporting electrolyte for preparing PCz-TEMPO electrode among the four supporting electrolytes. In addition, the electroactivity of PCz-TEMPO-TTFB electrode remained 94.6% after 100 scanning cycles in 0.1 M NaClO₄/CH₃CN solution.

设计并合成了具有侧链硝酰基自由基4-（9 H-咔唑-9-基）乙酰基氧基-2,2,6,6-四甲基哌啶-1-基氧基（Cz-TEMPO）的咔唑单体。相应的聚合物电极聚（咔唑-TEMPO）（PCz-TEMPO）已在CH _3中进行电化学制备具有不同支持电解质的CN溶液。PCz-TEMPO薄膜均匀分散在Pt电极表面，并通过FTIR，SEM，XPS和元素图谱进行表征。通过循环伏安法和原位FTIR光谱研究了PCz-TEMPO电极对苯甲醇氧化的电催化性能。四氟硼酸四丁基铵（TTFB）是四种支持电解质中制备PCz-TEMPO电极最有效的支持电解质。另外，在0.1 M NaClO ₄ / CH ₃ CN溶液中进行100个扫描循环后，PCz-TEMPO-TTFB电极的电活性保持94.6％。