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Novel primary phosphinecarboxamides derived from diamines
Dalton Transactions ( IF 3.5 ) Pub Date : 2021-4-28 , DOI: 10.1039/d1dt01198g
Erica N. Faria 1 , Andrew R. Jupp 1 , Jose M. Goicoechea 1
Affiliation  

We describe the synthesis of N-functionalised phosphinecarboxamides obtained by reaction of the 2-phosphaethynolate anion (PCO) with diamines, specifically hydrazine, methylenediamine and ethylenediamine, in the presence of acid. The resulting neutral compounds can be deprotonated to generate phosphide anions that, when further reacted with electrophiles, form secondary phosphines.

中文翻译:

衍生自二胺的新型伯膦酰胺

我们描述的合成Ñ -functionalised由2 phosphaethynolate阴离子(PCO的反应获得phosphinecarboxamides - )与二胺,尤其是肼,亚甲基二胺和乙二胺,在酸的存在下进行。所得的中性化合物可被去质子化以生成磷化物阴离子,当其与亲电试剂进一步反应时,可形成仲膦。
更新日期:2021-05-04
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