Organic/inorganic hybrid perovskite architectures have shown tremendous potential in the photovoltaic (PV) device community owing to the remarkable performance and concise solution-synthesized scheme. In the past decade, the perovskite solar cells (PSCs) achieved a significant improvement in the photovoltaic performances from a modest 3.81% to the recently certified highest values surpassing 24%. Nevertheless, issues constraining long-term stability and large-scale production still hinder the commercialization process of PSCs. Carbon nanomaterials, scoping from carbon-based quantum dots (QDs) to the two-dimensional graphene materials, have been widely utilized in perovskite device structures to enhance both the efficiency and stability of PSCs due to their outstanding chemical, electrical, and mechanical characteristics. In particular, the water-resistance property of specific carbon nanomaterials has significantly prevented the degradation of various function layers through impeding ambient moisture ingress, subsequently improving the long-term stability for PSCs. All of those unique properties have made nanocarbon one of the most potential materials to construct excellent photovoltaic performance PSCs with long-term stability. In this review, we conducted a comprehensive overview of extraordinary and notable efforts in implementing different carbon materials into individual function layers of perovskite device structure to simultaneously enhance their device efficiency and operating stability. Finally, we outline the prospects with a perspective on facing challenges and research directions of utilizing carbon materials in efficient and stable PSCs.

由于出色的性能和简洁的解决方案综合方案，有机/无机混合钙钛矿体系结构在光伏（PV）设备社区中显示出巨大潜力。在过去的十年中，钙钛矿太阳能电池（PSC）在光伏性能方面实现了显着提高，从适度的3.81％到最近认证的最高值超过24％。然而，制约长期稳定性和大规模生产的问题仍然阻碍了PSC的商业化进程。碳纳米材料从碳基量子点（QD）到二维石墨烯材料的范围，由于其出色的化学，电气和机械特性，已被广泛用于钙钛矿器件结构中，以提高PSC的效率和稳定性。特别地，特定的碳纳米材料的耐水性能通过阻止环境湿气的进入显着地防止了各种功能层的降解，从而改善了PSC的长期稳定性。所有这些独特的性能已使纳米碳成为构建具有长期稳定性的出色光伏性能PSC的最有潜力的材料之一。在这篇评论中，我们对将不同碳材料应用于钙钛矿器件结构的各个功能层中以同时提高其器件效率和操作稳定性的非凡和显着努力进行了全面而全面的概述。最后，我们以在高效，稳定的PSC中利用碳材料所面临的挑战和研究方向为视角，概述了前景。