Pillararene-based conjugated porous polymers,Polymer Chemistry

当前位置： X-MOL 学术 › Polym. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Pillararene-based conjugated porous polymers
Polymer Chemistry ( IF 4.1 ) Pub Date : 2021-3-30 , DOI: 10.1039/d1py00238d
Huacheng Zhang _{1,

2,

3,

4} , Jie Han _{4,

5,

6,

7,

8} , Chao Li _{4,

9,

10,

11}

Affiliation

The synthesis and application of promising polymeric materials–pillararene-based conjugated porous polymers–are discussed and summarized in this review. Two types of topological pillararene-based conjugated porous polymers were prepared including 1D linear and crosslinked ones. Different synthesis strategies and methods were employed including the formation of bulky heterocyclic moieties, Pd-catalyzed coupling reaction, Friedel–Crafts reaction, and substitution and condensation reactions. Additionally, the integration of pillararene subunits and COF into hybrid materials by noncovalent interactions was also described. By taking advantage of large BET surface areas, flexible porous polymers, and rigid chemical structures of pillararenes as well as their electron-rich cavities, pillararene-based conjugated porous polymers have various attractive applications in molecular recognition, sensors, removal of pollutants, gas adsorption, organic electrode materials, and heterogeneous catalysis.

中文翻译：

紫罗兰烯基共轭多孔聚合物

在这篇综述中讨论并总结了有前途的聚合材料（基于紫罗兰的共轭多孔聚合物）的合成和应用。制备了两种基于拓扑柱状芳烃的共轭多孔聚合物，包括一维线性和交联聚合物。采用了不同的合成策略和方法，包括形成庞大的杂环部分，Pd催化的偶联反应，Friedel-Crafts反应以及取代和缩合反应。另外，还描述了通过非共价相互作用将柱状芳烃亚基和COF整合到杂化材料中。通过利用大的BET表面积，柔性多孔聚合物，柱芳烃的刚性化学结构以及它们的富电子腔，

更新日期：2021-04-23

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南