Pre-magmatic continental extension often precedes the major magmatic expulsion of large igneous provinces (LIPs). However, the cause-and-effect relationship between pre-magmatic rifting and the extrusion of large amount of magma is controversial. It remains unclear whether magmatism arises as a consequence of passive rifting or whether it is related to active upwelling of the mantle. In addition, the relationship between the pre-magmatic stages and the final breakup, with the onset of conjugate passive margins, is ambiguous. In this study, we compiled available data from six LIPs (Central Atlantic, Karoo, Parana-Etendeka, Deccan, North Atlantic, and Afar igneous provinces) that successively occurred during the fragmentation of Pangea and found that pre-magmatic rift trends may show a high obliquity or even be orthogonal with respect to the future passive margins. We conclude that syn-magmatic rifts should not be directly correlated, both structurally and dynamically, to the ancient pre-magmatic rift phase. Furthermore, following the breakup of a supercontinent, seafloor spreading usually initiates within volcanic passive margins (VPMs) and then propagates away to create non-volcanic passive margins (NVPMs) as a consequence of the consumption and cooling of a sub-lithospheric positive thermal anomaly. Major transform faults often exist between VPMs and NVPMs, acting as a mechanical barrier to mantle melting and magmatism transportation.