Recyclable Copper Nanoparticles‐Catalyzed Hydroboration of Alkenes and β‐Borylation of α,β‐Unsaturated Carbonyl Compounds with Bis(Pinacolato)Diboron,Advanced Synthesis & Catalysis

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Recyclable Copper Nanoparticles‐Catalyzed Hydroboration of Alkenes and β‐Borylation of α,β‐Unsaturated Carbonyl Compounds with Bis(Pinacolato)Diboron
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2021-04-09 , DOI: 10.1002/adsc.202100394
Mahadev L. Shegavi ₁ , Suresh Saini ₁ , Ramesh Bhawar ₁ , Meghana Desai Vishwantha ₁ , Shubhankar Kumar Bose ₁

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The inside cover picture illustrates the magnetically separable Cu nanocatalyst for the β‐borylation of α,β‐unsaturated carbonyl compounds and anti‐Markovnikov‐selective hydroboration of alkenes, providing alkylboronate esters in high yields. The use of easy recyclable non‐noble metal nanoparticle based catalysts with high efficiency are in great demand from a standpoint of environmental and sustainable chemistry. Details of this work can be found in the full paper by Bose and co‐workers (M. L. Shegavi, S. Saini, R. Bhawar, M. D. Vishwantha, S. K. Bose, Adv. Synth. Catal. 2021, 363, xxx‐xxx; DOI: 10.1002/adsc.202001616).

中文翻译：

可回收铜纳米粒子催化烯烃的硼氢化反应和双（品那可乐）双硼的α，β-不饱和羰基化合物的β-硼化

的内封面图片示出了磁性可分离的Cu纳米催化剂为α，β不饱和羰基化合物和的β硼化抗烯烃-Markovnikov选择性硼氢化，以高收率提供alkylboronate酯。从环境和可持续化学的观点出发，迫切需要使用高效，易回收的非贵金属纳米颗粒基催化剂。这项工作的细节可以在百色和同事（ML Shegavi，S赛尼，R. Bhawar，MD Vishwantha，SK百色，全面的论文中找到。进阶合成器CATAL。2021， 363，XXX-XXX; DOI ：10.1002 / adsc.202001616）。

更新日期：2021-04-09

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