Molecular Catalysis ( IF 3.9 ) Pub Date : 2021-04-05 , DOI: 10.1016/j.mcat.2021.111539 Bin Wu , Shuguang Shen , Shujuan Yuan , Huajie Pan , Cui Wang , Shuaiqi Jing , Jing Li , Yansheng Zhao
High-performance carbon-based solid acid was prepared by a simple method. The effects of carbonization temperature and mixing ratio on the structure and performance of carbon catalysts were explored. The participation of borax increases both –COOH group and –SO3H group densities. In addition, graphitization and specific surface area of the catalyst increase by this co-carbonization method. Higher –COOH group density and aromaticity facilitate the adsorption between catalyst and substrate molecule through hydrogen bonding and CH-π interaction respectively. These improvements of structural significantly increase the hydrolysis activity of the catalyst.
中文翻译:
通过简单策略共同提高碳基固体酸中–COOH和–SO 3 H基的密度
通过简单的方法制备高性能的碳基固体酸。探讨了碳化温度和混合比对碳催化剂结构和性能的影响。硼砂的参与增加了–COOH基团和–SO 3 H基团的密度。另外,通过该共碳化方法,催化剂的石墨化和比表面积增加。较高的–COOH基团密度和芳香性分别通过氢键和CH-π相互作用促进催化剂和底物分子之间的吸附。这些结构上的改进显着提高了催化剂的水解活性。