All-solid-state lithium batteries are promising next-generation energy storage devices that have gained increasing attention in the past decades due to their huge potential towards higher energy density and safety. As a key component, solid electrolytes have also attracted significant attention and have experienced major breakthroughs, especially in terms of Li-ion conductivity. However, the poor electrode compatibility of solid electrolytes can lead to the degradation of electrolyte/electrode interfaces, which is the major cause for failure in all-solid-state lithium batteries. To address this, this review will summarize the in-depth understanding of physical and chemical interactions between electrolytes and electrodes with a focus on the contact, charge transfer and Li dendrite formation occurring at electrolyte/electrode interfaces. Based on mechanistic analyses, this review will also briefly present corresponding strategies to enhance electrolyte/electrode interfaces through compositional modifications and structural designs. Overall, the comprehensive insights into electrolyte/electrode interfaces provided by this review can guide the future investigation of all-solid-state lithium batteries.

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全固态锂电池中的电解质/电极界面：综述

全固态锂电池是有前途的下一代储能设备，由于其在提高能量密度和安全性方面的巨大潜力，在过去的几十年中受到越来越多的关注。作为关键成分，固体电解质也引起了广泛的关注，并取得了重大突破，特别是在锂离子电导率方面。但是，固体电解质的电极相容性差会导致电解质/电极界面的劣化，这是导致全固态锂电池发生故障的主要原因。为了解决这个问题，本综述将总结对电解质和电极之间的物理和化学相互作用的深入了解，重点是在电解质/电极界面处发生的接触，电荷转移和锂枝晶形成。基于机理分析，本综述还将简要介绍通过成分修饰和结构设计来增强电解质/电极界面的相应策略。总体而言，此评论提供的有关电解质/电极界面的全面见解可以指导未来对全固态锂电池的研究。

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