Applied Surface Science ( IF 6.3 ) Pub Date : 2021-04-02 , DOI: 10.1016/j.apsusc.2021.149701 Guojun Zheng , Zheng Xing , Xinran Gao , Chuanhao Nie , Zihan Xu , Zhicheng Ju
2D Cu-BDC MOF nanosheets were designed and synthesized by controlling the reaction time, and then annealed at different pyrolysis temperatures; the final MOF-derived carbons C500 (Final product at 500 °C) and C700 (Final product at 700 °C) were obtained by acid etching. Both carbon derivatives possessed abundant mesoporous structures which could facilitate ion migration and be conducive to the storage of lithium/potassium ions. C500 and C700 exhibited different dominant kinetic behaviors in lithium ion/potassium ion batteries. C500, which was controlled by diffusion process, showed better performance when used as anode material for lithium-ion batteries (LIBs). The C500 anode exhibited a reversible specific capacity of 690.4 mAhg-1 at a current density of 0.1 Ag-1. Even after 500 cycles at a current density of 5.0 Ag-1, the high specific capacity of 210.3 mAhg-1 was still maintained. C700, which was dominated by surface capacitance contribution, was a superior anode material for potassium-ion batteries (PIBs). The reversible specific capacity of C700 anode was maintained at 286.2 mAhg-1 at the current density of 0.1 Ag-1 after 100 cycles. Even after 500 cycles at a current density of 1.0 A g-1, C700 anode still maintained 170.8 mAhg-1.
中文翻译:
二维Cu-BDC MOF及其衍生的多孔碳作为高性能Li / K-离子电池负极材料的制备
通过控制反应时间设计合成二维Cu-BDC MOF纳米片,然后在不同的热解温度下进行退火。最终的MOF衍生碳C 500(最终产品在500°C)和C 700(最终产品在700°C)通过酸蚀刻获得。两种碳衍生物均具有丰富的中孔结构,可以促进离子迁移并有利于锂/钾离子的存储。C 500和C 700在锂离子/钾离子电池中表现出不同的主导动力学行为。通过扩散过程控制的C 500在用作锂离子电池(LIB)的负极材料时表现出更好的性能。C 500阳极表现出690.4 mAhg的可逆比容量-1 0.1 Ag构成的电流密度-1。即使在以5.0 Ag -1的电流密度进行500次循环之后,仍保持了210.3 mAhg -1的高比容量。以表面电容贡献为主的C 700是钾离子电池(PIB)的优质阳极材料。在100次循环后,在电流密度为0.1 Ag -1的情况下,C 700阳极的可逆比容量保持在286.2 mAhg -1。即使在以1.0 A g -1的电流密度进行500次循环之后,C 700阳极仍保持170.8 mAhg-1。