CuF₂ is considered a promising positive electrode material for fluoride-shuttle batteries (FSBs). Herein, the electrochemical compatibility of CuF₂ in an organic liquid electrolyte comprising equal concentrations (0.25 M) of lithium bis(oxalato)borate (LiBOB) and triphenylboroxine (TPhBX) in addition to saturated CsF salt in tetraethylene glycol dimethyl ether (G4) solution (LiBOB_0.25/TPhBX_0.25/sat_CsF/G4) was investigated for potential use in FSBs. CuF₂ in the LiBOB_0.25/TPhBX_0.25/sat_CsF/G4 system exhibited comparable initial discharge and charge capacities of 330 and 240 mAh g⁻¹, respectively. While XRD shows that some CuF₂ in the inner region of the electrode remains unreacted, XPS analysis clearly confirms the success of the conversion reaction at the electrode surface. In addition, almost no Cu was found in the LiBOB_0.25/TPhBX_0.25/sat_CsF/G4 electrolyte system in discharged and charged cells. Therefore, since the dissolution of CuF₂ and metallic Cu is alleviated through the use of the LiBOB_0.25/TPhBX_0.25/sat_CsF/G4 electrolyte, LiBOB_0.25/TPhBX_0.25/sat_CsF/G4 is a promising organic electrolyte system for FSBs.

CuF ₂被认为是用于氟化物穿梭电池（FSB）的有前途的正极材料。在此，除了在四甘醇二甲醚（G4）溶液中的饱和CsF盐外，CuF ₂在有机液体电解质中的电化学相容性，该电解质包含相等浓度（0.25 M）的双（草酸）硼酸锂（LiBOB）和三苯基环硼氧烷（TPhBX）。研究了（LiBOB _0.25 / TPhBX _0.25 / sat_CsF / G4）在FSB中的潜在用途。LiBOB _0.25 / TPhBX _0.25 / sat_CsF / G4系统中的CuF ₂表现出相当的初始放电容量和充电容量，分别为330和240 mAh g ^-1。XRD显示有些CuF在电极的内部区域中的图₂中未反应的情况下，XPS分析清楚地证实了在电极表面上的转化反应的成功。此外，在已放电和已充电电池的LiBOB _0.25 / TPhBX _0.25 / sat_CsF / G4电解质系统中几乎没有发现Cu 。因此，由于通过使用LiBOB _0.25 / TPhBX _0.25 / sat_CsF / G4电解质可减轻CuF ₂和金属Cu的溶解，因此LiBOB _0.25 / TPhBX _0.25 / sat_CsF / G4是一种有前途的用于FSB的有机电解质体系。