In this work, the MIL-100(Fe) was selected as blank-sample. Using one-pot method, phosphotungstic acids were encapsulated in the blank-sample to prepare HPW@MIL-100(Fe). Then, the ionic liquid ([EMIM][N(Tf)₂]) was chosen to modify the HPW@MIL-100(Fe). And the phosphotungstic acid-ionic-liquid (HPW-ILs) modified MIL-100(Fe) (HPW-ILs@MIL-100(Fe)) was obtained. The final product was introduced into polymer matrixes (C-SPAEKS) to prepare hybrid membranes. The structures and morphologies of MOFs and membranes were characterized by field emission scanning electron microscope (FTSEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). This series of membranes exhibited increasing proton conductivities from 0.043 S cm⁻¹ of C-SPAEKS to 0.138 S cm⁻¹ of HPW-ILs@MOF-4 at 100 °C and 100% relative humidity. Furthermore, these hybrid membranes have enhanced mechanical properties and dimensional stabilities. Obviously, the HPW-ILs@MIL-100(Fe) had a beneficial function on improving the performance of PEMs and showed great potential in PEMs applications.

在这项工作中，MIL-100（Fe）被选作空白样品。使用一锅法，将磷钨酸封装在空白样品中以制备HPW @ MIL-100（Fe）。然后，选择离子液体（[EMIM] [N（Tf）₂ ]）对HPW @ MIL-100（Fe）进行改性。并获得了磷钨酸-离子液体（HPW-ILs）改性的MIL-100（Fe）（HPW-ILs @ MIL-100（Fe））。将最终产品引入聚合物基质（C-SPAEKS）中以制备杂化膜。通过场发射扫描电子显微镜（FTSEM），傅立叶变换红外光谱（FTIR）和X射线衍射（XRD）表征了MOF和膜的结构和形态。该系列膜的质子电导率从C-SPAEKS的0.043 S cm ^-1增加到0.138 S cm ^-1在100°C和100％相对湿度下的HPW-ILs @ MOF-4的浓度。此外，这些杂化膜具有增强的机械性能和尺寸稳定性。显然，HPW-ILs @ MIL-100（Fe）对改善PEM的性能具有有益的作用，并在PEM应用中显示出巨大的潜力。