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Graphitic carbon nitride (g-C3N4) incorporated TiO2–B nanowires as efficient photoanode material in dye sensitized solar cells
Materials Chemistry and Physics ( IF 4.3 ) Pub Date : 2021-03-27 , DOI: 10.1016/j.matchemphys.2021.124520
Pronay Makal , Debajyoti Das

Graphitic carbon nitride (g-C3N4) nanosheets laminated TiO2–B nanowire composites (TNW/GCN) were synthesized adopting a simple pyrolysis process (500 °C), using melamine and hydrothermally grown TiO2–B NWs at different weight ratios. The TNW/GCN composites were used as efficient photoanode material in dye sensitized solar cells (DSSCs) and the systematic changes in the cell performance were investigated. The experimental results demonstrated a realistic improvement in the overall DSSC efficiency after modification of TiO2–B NWs with g-C3N4. Incorporation of optimum amount of g-C3N4 in the composite material could enhance the short circuit photocurrent density (JSC) as well as open circuit voltage (VOC). The DSSC based on TNW/GCN-10 photoanode enhanced the photocurrent conversion efficiency to 5.12% compared to 3.71% with TNW/GCN-0 photoanode (using pure TiO2–B NWs). This increased cell performance could be attributed to the suppression of recombination of the photogenerated electrons/hole charge pairs initiated by optimum g-C3N4 lamination of TiO2–B NWs photoanodes, in spite of subsequent lowering in the dye loading capacity.



中文翻译:

石墨化氮化碳(gC 3 N 4)掺入TiO 2 -B纳米线作为染料敏化太阳能电池中的有效光阳极材料

通过简单的热解工艺(500°C),使用三聚氰胺和水热生长的TiO 2 -B NW,以不同的重量比合成了石墨化的氮化碳(gC 3 N 4)纳米片,层压了TiO 2 -B纳米线复合材料(TNW / GCN)。TNW / GCN复合材料被用作染料敏化太阳能电池(DSSC)的有效光阳极材料,并研究了电池性能的系统变化。实验结果表明,用gC 3 N 4改性TiO 2 -B NWs后,总DSSC效率得到了实际改善。掺入最适量的gC 3 N 4复合材料中的碳纳米管可以提高短路光电流密度(J SC)和开路电压(V OC)。基于TNW / GCN-10光电阳极的DSSC将光电流转换效率提高到5.12%,而使用TNW / GCN-0光电阳极(使用纯TiO 2 -B NWs)则提高了3.71%。尽管随后降低了染料装载量,但这种提高的电池性能可能归因于抑制了由TiO 2 -B NWs光电阳极的最优gC 3 N 4层压引发的光生电子/空穴电荷对的重组。

更新日期:2021-04-04
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