Recent advances in probing host–guest interactions with solid state nuclear magnetic resonance,CrystEngComm

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Recent advances in probing host–guest interactions with solid state nuclear magnetic resonance
CrystEngComm ( IF 2.6 ) Pub Date : 2021-3-2 , DOI: 10.1039/d1ce00168j
Ashlea R. Hughes _{1,

2,

3,

4} , Frédéric Blanc _{1,

2,

3,

4,

5}

Affiliation

An overview of the recent role of solid state nuclear magnetic resonance (NMR) spectroscopy in the field of supramolecular chemistry to probe host–guest interactions is provided. Over the last few years, solid state NMR methodologies have delivered unique insights into the atomic level structure and dynamics of guest molecules adsorbed in solid materials that are not available by other approaches. This Highlight discusses the range of NMR interactions that enable access to this information and provides a number of illustrating examples that highlight their applications in a wide range of chemical systems and porous materials covering metal organic frameworks, porous molecular solids and zeolites.

中文翻译：

探测宿主与客体相互作用与固态核磁共振的最新进展

概述了固态核磁共振（NMR）光谱在超分子化学领域中探测宿主与客体相互作用的最新作用。在过去的几年中，固态NMR方法学已对吸附在固体材料中的客体分子的原子能级结构和动力学提供了独到的见解，而其他方法则无法实现。本要点讨论了可以访问此信息的NMR相互作用的范围，并提供了许多说明性示例，突出了它们在广泛的化学系统和覆盖金属有机骨架，多孔分子固体和沸石的多孔材料中的应用。

更新日期：2021-03-17

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