Abstract The reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization of vinyl acetate (VAc) mediated by methyl (methoxycarbonothioyl) sulfanyl acetate (MMSA) was carried out. The results showed that polymerizations initiated by AIBN and KPS proceeded in a controlled way. The RAFT miniemulsion polymerization of VAc initiated by KPS showed the shorter inhibition period, higher propagation rate coefficient and final conversion than those in experiment initiated by AIBN. When the monomer conversion reached 25%, the polydispersity index (PDI) of polymer became broad, which was related to chain transfer reaction in RAFT miniemulsion of VAc.

中文翻译：

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黄原酸酯介导的醋酸乙烯酯的可逆加成-断裂链转移（RAFT）微乳液聚合

摘要进行了乙酸甲酯（MMSA）介导的乙酸乙烯酯（VAc）的可逆加成-断裂链转移（RAFT）微乳液聚合。结果表明，由AIBN和KPS引发的聚合反应以受控方式进行。与AIBN引发的实验相比，KPS引发的VAc的RAFT细乳液聚合反应具有更短的抑制时间，更高的传播速率系数和最终转化率。当单体转化率达到25％时，聚合物的多分散指数（PDI）变宽，这与VAc的RAFT微乳液中的链转移反应有关。