Due to the high specific surface area and tunable pore size of Metal-Organic Frameworks (MOFs), the use of MOFs to catalyze CO2 conversion has increased in recent years. The present study is the first to use three MOFs of MIL types with free amino groups, namely, MIL-101-NH2(Cr), MIL-101-NH2(Al) and MIL-53-NH2(Al), for asymmetric electrocarboxylation of (1-chloroethyl)benzene with CO2. The electrochemical behavior of three MOFs were discussed. The optically active 2-phenylpropionic acid was obtained using t-Bu(R,R)salen(Co[II]) as the chiral mediate under mild conditions. In order to get the optimal results, the reaction conditions such as the influence of temperature, charge and the quantity of catalysts were investigated.

中文翻译：

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氨基官能化的MIL型金属有机骨架作为非均相催化剂，用于（1-氯乙基）苯与CO2的不对称电羧化

由于金属有机骨架（MOF）的高比表面积和可调节的孔径，近年来，使用MOF催化CO2转化的趋势有所增加。本研究是第一个使用具有游离氨基的MIL类型的三种MOF来进行不对称电羧化的MIL-101-NH2（Cr），MIL-101-NH2（Al）和MIL-53-NH2（Al） （1-氯乙基）苯与CO 2的混合物。讨论了三种MOF的电化学行为。使用t-Bu（R，R）salen（Co [II]）作为手性中间体，在温和条件下获得旋光性2-苯基丙酸。为了获得最佳结果，研究了反应条件，如温度，电荷和催化剂用量的影响。