Electrochemical reactions that take place at the interface between electrode and electrolyte involve charge transfer, mass transport, and phase transformation. Wetting or superwetting behaviors at multi-phase interfaces, including gas (bubbles), liquid (e.g., oil droplets), or solid (e.g., islands or film) states, largely interfere with the performance of related electrochemical energy conversion and storage devices, industrial production, and environmental protection. In this review, recent progress is summarized on interfacial interactions and the consequent superwetting behaviors at the electrode-electrolyte interfaces, which determine the affinity to products and reagents, charge transfer resistance, coverage of active sites, and fading of electrodes at large overpotentials. Furthermore, the construction strategies of superwetting electrodes and the future opportunities and challenges in superwettability-mediated chemistry are proposed.

在电极和电解质之间的界面发生的电化学反应涉及电荷转移，质量传输和相变。在多相界面上的润湿或超润湿行为，包括气体（气泡），液体（例如油滴）或固体（例如岛或膜）状态，在很大程度上干扰了相关的电化学能量转换和存储设备的性能，工业上生产，环保。在这篇综述中，关于电极相互作用和界面-电极界面上的超湿行为的最新进展总结了下来，这些行为决定了对产物和试剂的亲和力，电荷转移阻力，活性位点的覆盖以及在大的超电势下电极的褪色。此外，