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Ambient-Temperature Spin-State Switching Achieved by Protonation of the Amino Group in [Fe(H2Bpz2)2(bipy-NH2)]
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2016-07-29 00:00:00 , DOI: 10.1021/acs.inorgchem.6b01193
Yang-Hui. Luo 1 , Masayuki Nihei 2 , Gao-Ju Wen 1 , Bai-Wang Sun 1 , Hiroki Oshio 2
Affiliation  

Magnetism of a complex [Fe(H2Bpz2)2(bipy-NH2)] (H2Bpz2 = dihydrobis(1-pyrazolyl)borate, bipy-NH2 = 4,4′-diamino-2,2′-bipyridine) has been altered from paramagnetic to spin-crossover (SCO) behavior, through protonation of one amino group of bipy-NH2 with CF3SO3H. Complete SCO transition, both in solid state and in solution, occurs at ambient temperature.

中文翻译:

通过[Fe(H 2 Bpz 22(bipy-NH 2)]中的氨基质子化实现的环境温度自旋态转换

络合物[Fe(H 2 Bpz 22(bipy-NH 2)]的磁性(H 2 Bpz 2 =二氢双(1-吡唑基)硼酸酯,bipy-NH 2 = 4,4'-二氨基-2,2' -bipyridine)已通过bipy-NH 2的一个氨基与CF 3 SO 3 H质子化而从顺磁(SCO)行为改变为自旋交叉(SCO)行为。在环境和固态下均会发生SCO的完全转变温度。
更新日期:2016-07-29
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