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Composite energetic salt based on 3-nitramino-4-(1H-tetrazol-5-yl)furazan
Polyhedron Pub Date : 2020-12-01 , DOI: 10.1016/j.poly.2020.114810 Kun Zhao , Yameng Shi , Hongli Li , Haifeng Huang , Jun Yang
Polyhedron Pub Date : 2020-12-01 , DOI: 10.1016/j.poly.2020.114810 Kun Zhao , Yameng Shi , Hongli Li , Haifeng Huang , Jun Yang
Abstract The synthesis of high-energy–density energetic materials usually suffers from the conflict between energy and stability. The preparation of a 3-nitramino-4-(1H-5-tetrazol-5-yl)furazan based composite energetic salt with mixed cations was successfully achieved. The newly prepared composite energetic salt was fully characterized by IR, NMR, elemental analysis and single-crystal X-ray diffraction. Additionally, its thermal stability and sensitivities were measured and its detonation performances were calculated. The results show that this new salt has more balanced safety and detonation performances compared to its parent salts.
中文翻译:
基于3-nitramino-4-(1H-tetrazol-5-yl)furazan的复合含能盐
摘要高能密度含能材料的合成通常遭受能量与稳定性之间的矛盾。成功实现了基于3-nitramino-4-(1H-5-tetrazol-5-yl)呋喃山的混合阳离子高能盐的制备。通过IR,NMR,元素分析和单晶X射线衍射对新制备的复合高能盐进行了全面表征。另外,还测量了其热稳定性和敏感性,并计算了其爆炸性能。结果表明,与母盐相比,这种新盐具有更平衡的安全性和爆炸性能。
更新日期:2020-12-01
中文翻译:
基于3-nitramino-4-(1H-tetrazol-5-yl)furazan的复合含能盐
摘要高能密度含能材料的合成通常遭受能量与稳定性之间的矛盾。成功实现了基于3-nitramino-4-(1H-5-tetrazol-5-yl)呋喃山的混合阳离子高能盐的制备。通过IR,NMR,元素分析和单晶X射线衍射对新制备的复合高能盐进行了全面表征。另外,还测量了其热稳定性和敏感性,并计算了其爆炸性能。结果表明,与母盐相比,这种新盐具有更平衡的安全性和爆炸性能。