Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral‐at‐Cluster Photoluminescence,Angewandte Chemie International Edition

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Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral‐at‐Cluster Photoluminescence
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-03-08 , DOI: 10.1002/anie.202102851
Shinnosuke Horiuchi _{1,

2} , Sangjoon Moon ₁ , Akitaka Ito ₃ , Jacopo Tessarolo ₂ , Eri Sakuda _{1,

2} , Yasuhiro Arikawa ₁ , Guido H. Clever ₂ , Keisuke Umakoshi ₁

Affiliation

Multinuclear precious metal sandwich complexes containing an asymmetric center in the cluster are synthesized in the Research Article (DOI: 10.1002/anie.202101460) by Shinnosuke Horiuchi, Keisuke Umakoshi, and co‐workers. Reversible multipoint coordination in the cluster core can endow them a remarkable stability, allowing separation of enantiomers and detection of chiroptical properties of the sandwich complexes in solution.

中文翻译：

Pt复杂单元夹在中间的多核银团簇：通量行为和手性簇光致发光

Horiuchi的Shinnosuke Horiuchi，Umakoshi Keisuke和同事的研究文章（DOI：10.1002 / anie.202101460）中合成了在簇中包含不对称中心的多核贵金属夹心复合物。簇状核中可逆的多点配位可赋予它们非凡的稳定性，可分离对映异构体并检测溶液中夹心复合物的手性。

更新日期：2021-03-09

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