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Study of CO2Absorption Characteristic and Synthesis of 1-(2-methoxyethyl)-3-methylimidazoLium Methanesulfonate Ionic Liquid
Korean Chemical Engineering Research Pub Date : 2012-02-01 , DOI: 10.9713/kcer.2012.50.1.035
Yu Ran Jin , Yoon Ho Jung , So Jin Park , Il Hyun Baek

In this study, 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate ionic liquid has been synthesized, characterized and tested with respect to carbon dioxide absorption with the aim to use it as advanced absorbent materials in fossil fuel processing. The ionic liquid was synthesized by a one step method, low cost. The thermal and chemical stability of selected ionic liquid has been investigated by DSC, TGA and the structure was verified by -NMR spectroscopy. The solubility of carbon dioxide in the methanesulfonate-based ionic liquids were measured using a high-pressure equilibrium apparatus equipped with a variable-volume view cell at 30, 50 and and pressure up to 195 bar. The results show that carbon dioxide solubilities of 1-(2-methoxyethyl)-3-methylimidazolium methanesulfonate increased with pressure increasing and temperature decreasing, and the carbon dioxide absorption capacity showed 27.6 (g/kg) at , 13 bar.

中文翻译:

1-(2-甲氧基乙基)-3-甲基咪唑甲基磺酸锂离子液体的CO2吸收特性及合成研究

在这项研究中,已合成,表征和测试了1-(2-甲氧基乙基)-3-甲基咪唑鎓甲磺酸盐离子液体,旨在将其用作化石燃料加工中的高级吸收材料。通过一步法,低成本合成离子液体。所选离子液体的热稳定性和化学稳定性已通过DSC,TGA进行了研究,并通过-NMR光谱验证了结构。使用配备有可变体积观察室的高压平衡设备在30、50和最高195 bar的压力下测量二氧化碳在甲磺酸盐基离子液体中的溶解度。结果表明,甲磺酸1-(2-甲氧基乙基)-3-甲基咪唑鎓的二氧化碳溶解度随压力的升高和温度的降低而增加,
更新日期:2012-02-01
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