Click Chemistry with Cyclopentadiene,Chemical Reviews

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Click Chemistry with Cyclopentadiene
Chemical Reviews ( IF 51.4 ) Pub Date : 2021-03-02 , DOI: 10.1021/acs.chemrev.0c01055
Brian J Levandowski ₁ , Ronald T Raines ₁

Affiliation

Cyclopentadiene is one of the most reactive dienes in normal electron-demand Diels–Alder reactions. The high reactivities and yields of cyclopentadiene cycloadditions make them ideal as click reactions. In this review, we discuss the history of the cyclopentadiene cycloaddition as well as applications of cyclopentadiene click reactions. Our emphasis is on experimental and theoretical studies on the reactivity and stability of cyclopentadiene and cyclopentadiene derivatives.

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