The capable Pd complex immobilized on the functionalized polymeric scaffold for the green benzylation reaction,Applied Organometallic Chemistry

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The capable Pd complex immobilized on the functionalized polymeric scaffold for the green benzylation reaction
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-02-23 , DOI: 10.1002/aoc.6208
Maryam Ariannezhad ₁ , Davood Habibi ₁ , Somayyeh Heydari _{1,

2} , Vahideh Khorramabadi

Affiliation

The Pd complex immobilized on the functionalized polymeric support was prepared by the functionalization of the 4‐(benzyloxy)benzyl chloride polymer with 5‐phenyl‐1‐H‐tetrazole and the subsequent complexation with PdCl₂. Then, it was characterized with different methods and used as catalyst in the green benzylation reaction of various aryl cyanamides with benzyl bromide and K₂CO₃ in EtOH at 60°C for the appropriate times. Also, the antibacterial properties of the Pd polymer‐supported complex were studied against a number of gram‐positive and gram‐negative bacteria, and in some cases, it has the same effect as a tetracycline standard antibiotic against Bacillus thuringiensis (a gram‐positive bacterium) and Serratia marcescens (a gram‐negative bacterium).

中文翻译：

固定在功能化聚合物支架上的有能力的Pd复合物用于绿色苄基化反应

固定在官能化聚合物载体上的Pd配合物是通过4-（苄氧基）苄基氯聚合物与5-苯基-1- H-四唑的官能化反应以及随后与PdCl _2的络合制备的。然后，用不同的方法对其进行表征，并将其用作催化剂，在60℃下于EtOH中将各种芳基氰酰胺与苄基溴和K ₂ CO ₃进行绿色苄基化反应。此外，还研究了Pd聚合物支持的复合物对多种革兰氏阳性和革兰氏阴性细菌的抗菌性能，在某些情况下，其抗苏云金芽孢杆菌的四环素标准抗生素（革兰氏阳性）具有相同的作用。细菌）和粘质沙雷氏菌（革兰氏阴性细菌）。

更新日期：2021-02-23

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