Metals mainly exist in the form of complexes in urban wastewater, fresh water and even drinking water, which are difficult to remove and further harm human health. Fenton-like reaction has been used for the removal of metal complexes. Effective removal of metal complexes using Fenton-like reaction requires the removal of both metals and organic ligands, meanwhile, the fate of metals and organic pollutions must be clearly understood. Thus, this review summarizes the relevant research on metal complex removal from using Fenton-like reactions in the past ten years, with the detailed removal approaches and mechanisms analyzed. Electro-, photo-, microwave/ultrasound-Fenton reactions or the synergistic Fenton reaction have been shown to exhibit excellent metal complex treatment capabilities. Furthermore, various catalysts, such as transition metals, bimetals and metal-free catalytic systems can expand the potential applications of Fenton-like reactions. Novel Fenton reaction methods without the addition of metals or H₂O₂, with construction of a dual active center catalyst, or with the introduction of other free radicals, are all worthy of further investigation. Due to increasing levels of environmental metal and organic pollutions remediation requirements, more research is required for the development of economical and efficient novel Fenton-like processes.