Copper(I)–iodide cluster structures as functional and processable platform materials,Chemical Society Reviews

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Copper(I)–iodide cluster structures as functional and processable platform materials
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2021-2-18 , DOI: 10.1039/d0cs01470b
Javier Troyano _{1,

2,

3,

4} , Félix Zamora _{5,

6,

7,

8,

9} , Salomé Delgado _{5,

6,

7,

8,

9}

Affiliation

The combination of the copper(I)–iodide entity with organic ligands gives rise to a large variety of Cu^II polynuclear structures in the form of molecular complexes or extended structures. An appropriate selection of these components allows the preparation of materials showing interesting physicochemical properties and potential applications, mainly focused on organic light-emitting diodes and optical sensors. The most prominent physical feature of these materials is their emission, which can be modulated using the chemical structure and composition. This review article collates the advances in this research field, rationalizing the information into two main blocks as a function of the dimensionality of the structures: molecular complexes and extended networks. We describe the most typical ways of preparation, structures, and properties, with particular attention to the processability of the material as a fundamental aspect of the integration of the materials into real devices. Therefore, we aim to integrate the basic elements of the coordination chemistry of Cu^II clusters from the materials science perspective to envision this promising research field's potential technological future.

中文翻译：

铜（I）-碘化物簇结构作为功能性和可加工平台材料

铜的组合（我）与有机配体-碘化物实体产生了大量的各种铜的^我我以分子复合物或扩展结构形式的多核结构。这些部件中的一个适当的选择允许的表示有趣的物理化学性质和潜在的应用材料的制备中，主要集中在有机发光二极管和光学传感器。这些材料最突出的物理特征是它们的发射，可以使用化学结构和组成对其进行调节。这篇综述文章总结了该研究领域的进展，根据结构的维数将信息合理化为两个主要模块：分子复合物和扩展网络。我们描述了最典型的制备方法，结构和特性，特别注意将材料的可加工性作为将材料集成到实际设备中的基本方面。因此，我们旨在整合铜的配位化学的基本元素^我从材料科学的角度出发，对这个有前途的研究领域的潜在技术未来进行展望。

更新日期：2021-02-19

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