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Synthesis of 5-(1H-pyrazol-1-yl)-2H-tetrazole-derived energetic salts with high thermal stability and low sensitivity
Energetic Materials Frontiers ( IF 3.3 ) Pub Date : 2020-09-06 , DOI: 10.1016/j.enmf.2020.08.004
Yue Zheng , Xia Zhao , Xiujuan Qi , Kangcai Wang , Tianlin Liu

In this study, a novel energetic compound 3-nitro-1-(2H-tetrazol-5-yl)-1H-pyrazole-4-carboxylic acid (1) and a series of corresponding energetic salts (24) were designed and synthesized. Their chemical structures were determined through NMR spectra, elemental analysis, FT-IR, and single crystal X-ray diffraction. All of these energetic compounds displayed low sensitivity to impact (IS ​> ​40 ​J) and friction (FS ​> ​240 ​N) and acceptable detonation properties. Compound 13 showed high thermal stability, with decomposition temperatures higher than 300 ​°C. In addition, the structure–property relationship of these compounds was elucidated by crystal stacking analyses combined with energetic performance parameters. In this way, a new approach for the development of novel energetic materials can be provided given the high performance of these energetic compounds.



中文翻译:

具有高热稳定性和低灵敏度的5-(1 H-吡唑-1-基)-2 H-四唑衍生的高能盐的合成

在这项研究中,一种新型的高能化合物的3-硝基-1-(2- ħ -四唑-5-基)-1- ħ吡唑-4-羧酸(1)和一系列相应的高能盐(的2 - 4)为设计和合成。它们的化学结构通过NMR光谱,元素分析,FT-IR和单晶X射线衍射确定。所有这些高能化合物对冲击(IS> 40 J)和摩擦(FS> 240 N)的敏感性都很低,并且具有可接受的爆炸特性。化合物1 - 3具有较高的热稳定性,分解温度高于300°C。另外,通过晶体堆积分析结合高能性能参数阐明了这些化合物的结构-性质关系。这样,鉴于这些高能化合物的高性能,可以提供一种开发新型高能材料的新方法。

更新日期:2020-09-06
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