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Formation of Carbon-Nitrogen Bond Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions
Current Organic Chemistry ( IF 1.7 ) Pub Date : 2020-12-31 , DOI: 10.2174/1385272822999201117154919
Yaxin O Yang 1 , Xi Wang 1 , Jiaxi Xiao 1 , Yadong Li 1 , Fengxia Sun 2 , Yunfei Du 1
Affiliation  

In the past several decades, hypervalent iodine chemistry has witnessed prosperous development as hypervalent iodine reagents have been widely used in various organic transformations. Specifically, hypervalent iodine reagents have been vastly used in various bondforming reactions. Among these oxidative coupling reactions, the reactions involving the formation of C-N bond have been extensively explored to construct various heterocyclic skeletons and synthesize various useful building blocks. This review article is to summarize all the transformations in which carbon-nitrogen bond formation occurred by using hypervalent iodine reagents under metal-free conditions.



中文翻译:

无金属条件下高价碘试剂介导的碳氮键的形成

在过去的几十年中,由于高价碘试剂已广泛用于各种有机转化中,因此高价碘化学得到了长足的发展。具体地说,高价碘试剂已广泛用于各种成键反应中。在这些氧化偶联反应中,已经广泛地探索了涉及CN键形成的反应以构建各种杂环骨架并合成各种有用的结构单元。这篇综述文章总结了在无金属条件下使用高价碘试剂发生碳-氮键形成的所有转变。

更新日期:2021-02-01
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