Rhodium-catalyzed carbonylative coupling of alkyl halides with thiols: a radical process faster than easier nucleophilic substitution,Chemical Communications

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Rhodium-catalyzed carbonylative coupling of alkyl halides with thiols: a radical process faster than easier nucleophilic substitution
Chemical Communications ( IF 4.3 ) Pub Date : 2021-1-8 , DOI: 10.1039/d0cc07578g
Han-Jun Ai _{1,

2,

3,

4} , Jabor Rabeah _{1,

2,

3,

4} , Angelika Brückner _{1,

2,

3,

4} , Xiao-Feng Wu _{1,

2,

3,

4,

5}

Affiliation

How to make a carbonylative coupling faster than the easier nucleophilic substitution? In this communication, a rhodium-catalyzed radical-based carbonylative coupling of alkyl halides with thiolphenols has been realized. Thioesters were isolated in good yields in general.

中文翻译：