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Superhydrophobic modification of cellulose sponge fabricated from discarded jute bags for oil water separation
Journal of Environmental Chemical Engineering ( IF 7.4 ) Pub Date : 2021-01-13 , DOI: 10.1016/j.jece.2021.105063
Dheeraj Ahuja , Shiva Dhiman , Gaurav Rattan , Sheetal Monga , Sonal Singhal , Anupama Kaushik

Recent oil spills endanger the aquatic ecosystem besides huge loss of natural resources, hence require immediate attention. To develop economical solution for combating oil spills, discarded jute bags, with 60–65% cellulose were used to fabricate cellulose sponge using sol-gel method followed by freeze drying. The sponge surface was rendered superhydrophobic by dip coating with Tetraethyl-orthosilicate/Hexadecyltrimethoxy Silane (TEOS/HDTMS). The pristine and dip coated hydrophobic cellulose sponge (DHCS) were characterized for structure, morphology and hydrophobicity. FE-SEM confirmed the hydrophobic coating of TEOS/HDTMS on sponge surface, while superhydrophobicity was established with static contact angle of 151°. DHCS exhibited oil water separation efficiency of 98.5% and 97.2% and equilibrium adsorption efficiency of 35.55 g/g and 31.37 g/g for diesel oil and motor oil, respectively. The adsorption follow pseudo-second order kinetics with regression coefficients, R2 > 0.99. Equilibrium studies indicated that the Freundlich isotherm was best fit isotherm for oil water removal by DHCS. DHCS displayed significant recyclability with slight reduction of adsorption capacity to 85.2% for diesel oil and 82.5% for motor oil of its initial value after 10 cycles.



中文翻译:

用废弃黄麻袋制成的纤维素海绵的超疏水改性,用于油水分离

除了自然资源的巨大损失外,最近的漏油事件还危害着水生生态系统,因此需要立即予以关注。为了开发出经济有效的解决油泄漏的解决方案,使用了60-65%纤维素的废弃黄麻袋,采用溶胶-凝胶法,然后进行冷冻干燥,来制造纤维素海绵。通过用原硅酸四乙酯/十六烷基三甲氧基硅烷(TEOS / HDTMS)浸涂使海绵表面具有超疏水性。对原始和浸涂的疏水性纤维素海绵(DHCS)的结构,形态和疏水性进行了表征。FE-SEM证实了TEOS / HDTMS在海绵表面具有疏水性,而超疏水性则建立在151°的静态接触角上。DHCS的油水分离效率为98.5%和97.2%,平衡吸附效率为35.55 g / g和31。柴油和机油分别为37 g / g。吸附遵循伪二级动力学,具有回归系数R2 > 0.99。平衡研究表明,Freundlich等温线最适合用DHCS去除油水。DHCS在10个循环后显示出显着的可回收性,其对柴油的吸附能力略有下降,分别降至85.2%和82.5%。

更新日期:2021-01-22
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