A New Family of Polyoxometalates: Tris-functionalized Lindqvist-Type Hexatungstovanadates,Inorganic Chemistry

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A New Family of Polyoxometalates: Tris-functionalized Lindqvist-Type Hexatungstovanadates
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2021-01-05 , DOI: 10.1021/acs.inorgchem.0c02726
Bo Huang _{1,

2} , Yu Wang ₁ , Zicheng Xiao ₁ , Degang Ke ₁ , Min Cheng ₁ , Pingfan Wu ₁

Affiliation

We successfully designed and obtained a new family of polyoxometalates (POMs) containing mixed-metal elements and a trialkoxyl (TRIS) ligand via a very simple one-pot process under mild condition. Single-crystal X-ray diffraction revealed that this family belongs to compact Lindqvist-type hexatungstovanadates. In particular, the hydroxyl-containing product can be further functionalized through esterification. Not only does this work open a broad door for unusual POM clusters involving vanadium and tungsten atoms in the future, but also the design concept of this work also provides new insight for the synthesis and further exploration of POMs.

中文翻译：

多金属氧酸盐的新家族：Tris功能化的Lindqvist型六钒钒酸盐

我们在温和的条件下通过非常简单的一锅法成功设计并获得了一个新的多金属氧酸盐（POM）系列，其中包含混合金属元素和三烷氧基（TRIS）配体。X射线单晶衍射表明该族属于致密的Lindqvist型六钨杂钒酸盐。特别地，含羟基的产物可以通过酯化进一步官能化。这项工作不仅为将来涉及钒和钨原子的不寻常的POM团簇打开了广阔的大门，而且这项工作的设计理念也为POM的合成和进一步探索提供了新的见识。

更新日期：2021-01-18

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