Coordination Chemistry Reviews ( IF 20.3 ) Pub Date : 2021-01-06 , DOI: 10.1016/j.ccr.2020.213735 Ming-Xue Wu , Yan Wang , Guohui Zhou , Xiaomin Liu
The research for metal organic frameworks (MOFs)- and covalent organic frameworks (COFs)-based functional composites has attracted continuous attention due to their excellent synergistic properties. With the increasing interest in expanding the diversity and properties of multi-component framework materials, the commonness and uniqueness of MOFs and COFs build a bridge for the potential development of meritorious MOFs-COFs composites. This minireview comprehensively introduced the recent development of MOFs-COFs composites from their syntheses to enhanced applications. Starting from the preparation methods, MOFs-mediated MOF@COF composites and COFs-mediated COF@MOF composites fabricated under various synthetic conditions are introduced, respectively. Furthermore, the enhanced application performance of the MOF@COF composites and COF@MOF composites in catalysis and their potential applications in adsorption and separation, energy storage and sensing are summarized. Followed by the above discussion, we further highlight the opportunities and challenges faced by MOFs-COFs composites. Altogether, this minireview is expected to provide inspiration for the development of the dazzling but embryonic MOFs-COFs composites.
中文翻译:
来自世界各地的火花:MOF和COF的合作
基于金属有机骨架(MOF)和基于共价有机骨架(COF)的功能复合材料的研究由于其出色的协同性能而引起了持续的关注。随着人们对扩大多组分骨架材料的多样性和性能的兴趣日益浓厚,MOF和COF的共性和独特性为立功MOFs-COFs复合材料的潜在发展搭建了一座桥梁。这份简短的综述全面介绍了MOFs-COFs复合材料从合成到增强应用的最新进展。从制备方法出发,分别介绍了在各种合成条件下制备的MOFs介导的MOF @ COF复合材料和COFs介导的COF @ MOF复合材料。此外,总结了MOF @ COF复合材料和COF @ MOF复合材料在催化中的增强应用性能,以及它们在吸附,分离,储能和传感方面的潜在应用。在上述讨论之后,我们进一步强调了MOFs-COFs复合材料所面临的机遇和挑战。总而言之,这份小型综述有望为令人眼花but乱但萌芽的MOFs-COFs复合材料的开发提供灵感。