In the present work, we have carried out experimental analysis along with first-principles density functional theory (DFT) calculations to understand the magnetic ground state of Fe doped Mn₂O_3. The analysis of structural properties show that the orthorhombic type of crystal structure with space group Pcab is preserved, but the unit cell volume decreases with an increase in Fe concentration. Magnetic susceptibility measurements show that two antiferromagnetic transitions (T_N1 = 25 K, T_N2 = 80 K) for undoped Mn₂O₃ merged into one at around 35 K with increasing concentration of Fe doping (Mn_2−xFe_xO₃; x = 0; 0.20; 0.50; 0.75). M-H curve at 5 K exhibits small hysteresis around the origin. The magnitude of magnetization increases with the increasing concentration of Fe. M-H curve at 100 K shows the linear behavior of M concerning H for x = 0.20 and x = 0.50, indicating the paramagnetic state of the sample. As a complement to the experimental analysis, first-principles calculations using DFT were carried out. Fe doping was simulated by the corresponding substitution of Mn atoms to reproduce stoichiometric features of Mn_2−xFe_xO_3. The agreement between the two approaches suggests that the magnetic ground state of Fe doped Mn₂O₃ is tunable with Fe concentration.