4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics,Journal of the American Chemical Society

当前位置： X-MOL 学术 › J. Am. Chem. Soc. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2020-12-29 , DOI: 10.1021/jacs.0c11138
Yan Liu _{1,

2} , Xiao-Lan Chen ₁ , Xiao-Yun Li ₁ , Shan-Shan Zhu ₁ , Shi-Jun Li ₁ , Yan Song ₁ , Ling-Bo Qu ₁ , Bing Yu ₁

Affiliation

2,4,5,6-Tetrakis(3,6-di-tert-butyl-9H-carbazol-9-yl)isophthalonitrile (4CzIPN-tBu) was developed as a photocatalyst for the phosphorus-radical-initiated cascade cyclization reaction of isocyanides. By using 4CzIPN-tBu as catalyst, we developed a visible-light-induced proton-coupled electron transfer strategy for the generation of phosphorus-centered radicals, via which a wide range of phosphorylated phenanthridines, quinolines, and benzothiazoles were successfully constructed.

中文翻译：

4CzIPN-tBu 催化的质子耦合电子转移用于磷酸化 N-杂芳烃的光合作用

2,4,5,6-四（3,6-二叔丁基-9H-咔唑-9-基）间苯二甲腈（4CzIPN-tBu）被开发作为磷自由基引发的级联环化反应的光催化剂异氰化物。通过使用 4CzIPN-tBu 作为催化剂，我们开发了一种用于产生以磷为中心的自由基的可见光诱导质子耦合电子转移策略，通过该策略成功构建了广泛的磷酸化菲啶、喹啉和苯并噻唑。

更新日期：2020-12-29

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南