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Contemporary methods for generation of aryl radicals
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-12-14 , DOI: 10.1039/d0cs00589d Nikita Kvasovs 1 , Vladimir Gevorgyan 1
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2020-12-14 , DOI: 10.1039/d0cs00589d Nikita Kvasovs 1 , Vladimir Gevorgyan 1
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The synthetic utility of aryl radicals has been established in the last century, however, their broad applications were hampered by ineffective generation methods. It was in the last decade, that a rapid development of various redox systems took place, thus triggering a renaissance of aryl radical chemistry. This tutorial review focuses on the start-of-the-art methods for generation of aryl radicals. Primarily, various light-induced systems, including photoredox catalysis, visible light transition metal catalysis, and chemistry of electron donor–acceptor complexes, are reviewed. The main current precursors of aryl radicals are evaluated together with the selected examples of their modern applications.
中文翻译：
产生芳基自由基的现代方法
芳基自由基的合成效用已在上个世纪确立，然而，它们的广泛应用受到无效生成方法的阻碍。正是在过去的十年中，各种氧化还原系统得到了快速发展，从而引发了芳基自由基化学的复兴。本教程回顾重点介绍了生成芳基自由基的最先进方法。首先，综述了各种光诱导系统，包括光氧化还原催化、可见光过渡金属催化和电子供体-受体复合物的化学。芳基自由基的当前主要前体与它们现代应用的选定实例一起进行了评估。
更新日期：2020-12-14
中文翻译：
产生芳基自由基的现代方法
芳基自由基的合成效用已在上个世纪确立，然而，它们的广泛应用受到无效生成方法的阻碍。正是在过去的十年中，各种氧化还原系统得到了快速发展，从而引发了芳基自由基化学的复兴。本教程回顾重点介绍了生成芳基自由基的最先进方法。首先，综述了各种光诱导系统，包括光氧化还原催化、可见光过渡金属催化和电子供体-受体复合物的化学。芳基自由基的当前主要前体与它们现代应用的选定实例一起进行了评估。
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