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Direct Synthesis of Multi(boronate) Esters from Alkenes and Alkynes via Hydroboration and Boration Reactions
ACS Catalysis ( IF 11.3 ) Pub Date : 2020-12-10 , DOI: 10.1021/acscatal.0c03418 Xianjin Wang 1, 2 , Yue Wang 1 , Wei Huang 3 , Chungu Xia 1 , Lipeng Wu 1
ACS Catalysis ( IF 11.3 ) Pub Date : 2020-12-10 , DOI: 10.1021/acscatal.0c03418 Xianjin Wang 1, 2 , Yue Wang 1 , Wei Huang 3 , Chungu Xia 1 , Lipeng Wu 1
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Multi(boronate) esters have been attracting increasing attention as versatile building blocks for the succinct and precise synthesis of complex molecules. However, there are a limited number of efficient synthetic procedures available. In this respect, the direct multiboration of alkenes and alkynes is undoubtedly an ideal route for their synthesis. During the past 30 years, catalytic systems based on transition-metals, organophosphines, bases, and even catalyst-free systems, with heat or with light irradiation for their straightforward preparation from alkenes and alkynes have been developed. Multi(boronate) esters with different numbers (up to 4) and positional relationships of the adjacent boron moieties were obtained, which are summarized and discussed herein.
中文翻译：
通过硼氢化和硼化反应直接从烯烃和炔烃中合成多硼酸酯
作为复杂分子的简洁精确合成的多功能构建基，多（硼酸酯）酯已引起越来越多的关注。但是，可用的有效合成程序数量有限。在这方面，烯烃和炔烃的直接多硼化无疑是它们合成的理想途径。在过去的30年中，已经开发出了基于过渡金属，有机膦，碱，甚至不含催化剂的体系的催化体系，该体系通过加热或光辐射直接从烯烃和炔烃制备。获得了具有不同数量（至多4个）和相邻硼部分的位置关系的多（硼酸酯）酯，其在本文中进行了总结和讨论。
更新日期：2021-01-01
中文翻译：
通过硼氢化和硼化反应直接从烯烃和炔烃中合成多硼酸酯
作为复杂分子的简洁精确合成的多功能构建基，多（硼酸酯）酯已引起越来越多的关注。但是，可用的有效合成程序数量有限。在这方面，烯烃和炔烃的直接多硼化无疑是它们合成的理想途径。在过去的30年中，已经开发出了基于过渡金属，有机膦，碱，甚至不含催化剂的体系的催化体系，该体系通过加热或光辐射直接从烯烃和炔烃制备。获得了具有不同数量（至多4个）和相邻硼部分的位置关系的多（硼酸酯）酯，其在本文中进行了总结和讨论。
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