Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-12-11 , DOI: 10.1016/j.cplett.2020.138271
Cátia L. Ücker , Fábio C. Riemke , Nivaldo F. de Andrade Neto , Anderson de A.G. Santiago , Tatiane J. Siebeneichler , Neftali L.V. Carreño , Mario L. Moreira , Cristiane W. Raubach , Sergio Cava
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This work demonstrates the application of crystalline Nb2O5 powders with different phases as photocatalysts in the degradation of Rhodamine B (RhB). The crystalline structure and the corresponding surface area of Nb2O5 changed with an increase in the heat-treatment temperature, leading to different photocatalytic activities. Thus, for Nb2O5 with low crystallinity, the total degradation of RhB on pseudohexagonal Nb2O5 is 97%, whereas that on orthorhombic Nb2O5 is 57%. The degradation products of RhB were identified from the results of high-performance liquid chromatography, mass spectrometry, and total organic content analysis, and the possible photocatalytic degradation pathways are proposed.
中文翻译:

Nb 2 O 5晶体结构对光催化效率的影响
这项工作证明了具有不同相的结晶Nb 2 O 5粉末作为光催化剂在罗丹明B(RhB)降解中的应用。Nb 2 O 5的晶体结构和相应的表面积随热处理温度的升高而变化,从而导致不同的光催化活性。因此,Nb的2 ö 5具有低结晶度,罗丹明B上伪六边形的Nb的总降解2 ö 5是97%,而上斜方晶的Nb 2 ö 5是57%。从高效液相色谱,质谱和总有机物含量分析结果确定了RhB的降解产物,并提出了可能的光催化降解途径。