Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-12-11 , DOI: 10.1016/j.cplett.2020.138273 Liang Bao , Yuming Shi , Wangfeng Bai , Shiting Wu , Yongjun Yuan
Bismuth Titanite (Bi4Ti3O12) platelets with surface defects were successfully synthesized via a simple ball milling route. The additive Li with strong reducibility stripped off the surface atoms from the (Bi2O2)2+ slabs and even (Bi2Ti3O10)2− perovskite layers, leaving abundant surface defects. The defect-rich Bi4Ti3O12 platelets with a narrowed band gap achieved excellent degradability, capable of degrading Rhodamine B (RhB) completely within 25 min under visible light irradiation. The results of this study demonstrated the extraordinary photodegradation performance of micro-sized catalysts.
中文翻译:
实现富含表面缺陷的Bi 4 Ti 3 O 12血小板的优异可见光光催化活性
通过简单的球磨工艺成功地合成了具有表面缺陷的铋钛矿(Bi 4 Ti 3 O 12)薄片。具有强还原性的添加剂Li从(Bi 2 O 2)2+平板甚至(Bi 2 Ti 3 O 10)2-钙钛矿层剥离了表面原子,从而留下了大量的表面缺陷。富缺陷的Bi 4 Ti 3 O 12带隙较窄的血小板具有出色的降解性,能够在可见光照射下在25分钟内完全降解若丹明B(RhB)。这项研究的结果证明了微尺寸催化剂的非凡的光降解性能。