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Hydrosilylation of allyl glycidyl ether with triethoxysilane
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2007-01-01 , DOI: 10.1134/S1070363207010082
E. A. Chernyshev , Z. V. Belyakova , L. K. Knyazeva , N. N. Khromykh

Hydrosilylation of allyl glycidyl ether with triethoxysilane in presence of Speier’s catalyst leads to triethoxy(3-glycidoxypropyl)silane and triethoxy(2-glycidoxy-1-methylethyl)silane and is accompanied by isomerization of allyl glycidyl ether and cleavage of the oxirane ring and the ether bond. An effect of admixtures in allyl glycidyl ether on the process is revealed. Some other hydrosilylation catalysts and additives to Speier’s catalyst are studied

中文翻译:

烯丙基缩水甘油醚与三乙氧基硅烷的氢化硅烷化

在Speier催化剂的存在下,烯丙基缩水甘油醚与三乙氧基硅烷的硅氢加成反应会生成三乙氧基(3-缩水甘油氧基丙基)硅烷和三乙氧基(2-缩水甘油氧基-1-甲基乙基)硅烷,并伴有烯丙基缩水甘油醚的异构化和环氧乙烷环的裂解和醚键。揭示了烯丙基缩水甘油醚中的混合物对该方法的影响。研究了其他一些氢化硅烷化催化剂和Speier催化剂的添加剂
更新日期:2007-01-01
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