当前位置: X-MOL 学术Inorg. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
A Second Modification of Beryllium Bromide: β-BeBr2
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2020-11-13 , DOI: 10.1021/acs.inorgchem.0c02832
Magnus R. Buchner 1 , Fabian Dankert 2 , Nils Spang 1 , Florian Pielnhofer 3 , Carsten von Hänisch 2
Affiliation  

The synthesis of a second beryllium bromide modification, β-BeBr2, was accomplished through recrystallization of α-BeBr2 from benzene in the presence of cyclo-decamethylpentasiloxane. This phase was analyzed via single-crystal X-ray diffraction and IR and Raman spectroscopy as well as density functional theory calculations. This enabled a comparison to α-BeBr2 and the α and β phases of beryllium chloride and iodide.

中文翻译:

溴化铍的第二变形例:β-BeBr 2

第二溴化铍变形例的合成,β-BeBr 2,通过α-BeBr的重结晶来完成2从苯中的存在-decamethylpentasiloxane。通过单晶X射线衍射,IR和拉曼光谱以及密度泛函理论计算来分析该相。这使比较,以α-BeBr 2和α,铍氯化物和碘化物的β相。
更新日期:2020-12-07
down
wechat
bug