As a subseries of the covalent organic framework (COF) material family, polyimide‐based covalent organic framework (PI‐COF) material, which has the advantages of high stability of polyimide, high specific surface area, and controllable pores of COF material, is expected to be a new type of porous material with potential applications. Although the development of PI‐COF is in the early stages during the past decade, it has attracted extensive attention and is widely used in heterogeneous catalysis, gas separation, and storage fields. Therefore, this review is aiming to give a comprehensive understanding of the recent progress of PI‐COFs. This article summarizes the progress of PI‐COF from three aspects: controllable structure design, synthesis method, and application. First of all, under the guidance of network chemical design principles, the topology type of PI‐COF and the size and shape of the formed pores are summarized in terms of different organic monomers. Then the five synthetic strategies for the synthesis of PI‐COF are analyzed. Finally, the applications of PI‐COF in adsorption and separation, drug delivery, solar‐to‐electrochemical energy storage, photocatalysis, and electrocatalyst are introduced.

中文翻译：

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聚酰亚胺共价有机骨架的设计与合成

作为共价有机骨架（COF）材料家族的子系列，基于聚酰亚胺的共价有机骨架（PI-COF）材料具有聚酰亚胺高稳定性，高比表面积和可控COF材料孔隙的优点。有望成为具有潜在应用的新型多孔材料。尽管PI‐COF的开发处于过去十年的初期，但它已经引起了广泛的关注，并广泛用于非均相催化，气体分离和存储领域。因此，本次审查旨在全面了解PI-COF的最新进展。本文从可控结构设计，合成方法和应用三个方面总结了PI‐COF的进展。首先，在网络化学设计原则的指导下，根据不同的有机单体总结了PI‐COF的拓扑类型以及形成的孔的大小和形状。然后分析了PI-COF合成的五种合成策略。最后，介绍了PI-COF在吸附和分离，药物输送，太阳能到电化学能量存储，光催化和电催化剂中的应用。