Cobalt bis(2‐ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins,Applied Organometallic Chemistry

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Cobalt bis(2‐ethylhexanoate) and terpyridine derivatives as catalysts for the hydrosilylation of olefins
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2020-10-12 , DOI: 10.1002/aoc.6027
Zinan Dai ₁ , Zehao Yu ₁ , Ying Bai ₁ , Jiayun Li ₁ , Jiajian Peng ₁

Affiliation

A simple method for the hydrosilylation of olefins by using air‐stable cobalt catalysts is developed. The catalyst system is composed of simple, cheap, and readily available cobalt(II) salts and well‐defined terpyridine derivatives as cocatalysts or ligands, and the hydrosilylation processes can be processed smoothly under mild conditions without either Grignard reagents or NaHBEt₃ as activator.

中文翻译：

双（2-乙基己酸）钴和三联吡啶衍生物作为烯烃氢化硅烷化的催化剂

开发了一种使用空气稳定的钴催化剂进行烯烃加氢硅烷化的简单方法。该催化剂体系由简单，廉价且易于获得的钴（II）盐和定义明确的三联吡啶衍生物作为助催化剂或配体组成，并且氢化硅烷化过程可以在温和条件下顺利进行，而无需使用格氏试剂或NaHBEt ₃作为活化剂。

更新日期：2020-10-12

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