In recent years, Prussian blue analogue (PBA) materials have been widely explored and investigated in energy storage/conversion fields. Herein, the structure/property correlations of PBA materials as host frameworks for various charge‐carrier ions (e.g., Na⁺, K⁺, Zn²⁺, Mg²⁺, Ca²⁺, and Al³⁺) is reviewed, and the optimization strategies to achieve advanced performance of PBA electrodes are highlighted. Prospects for further applications of PBA materials in proton, ammonium‐ion, and multivalent‐ion batteries are summarized, with extra attention given to the selection of anode materials and electrolytes for practical implementation. This work provides a comprehensive understanding of PBA materials, and will serve as a guidance for future research and development of PBA electrodes.

中文翻译：

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普鲁士蓝类似物的结构和性质在储能和转化中的应用

近年来，普鲁士蓝类似物（PBA）材料在能量存储/转换领域得到了广泛的探索和研究。本文中，作为各种电荷载流子离子（例如Na ⁺，K ⁺，Zn 2 ⁺，Mg 2 ⁺，Ca ²⁺和Al ^3+）的宿主框架的PBA材料的结构/性质相关性），并重点介绍了实现PBA电极先进性能的优化策略。总结了PBA材料在质子，铵离子和多价离子电池中的进一步应用前景，并特别注意了阳极材料和电解质的选择以实际实施。这项工作提供了对PBA电极材料的全面理解，并将为将来对PBA电极的研究和开发提供指导。