Sulfoxonium ylides: simple compounds with chameleonic reactivity,Organic & Biomolecular Chemistry

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Sulfoxonium ylides: simple compounds with chameleonic reactivity
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2020-10-01 , DOI: 10.1039/d0ob01822h
Giorgiana Denisa Bisag ₁ , Silvia Ruggieri , Mariafrancesca Fochi , Luca Bernardi

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Sulfur ylides first disclosed in 1930 started to gain more attention in the 1960s, thanks mainly to the studies by Corey and Chaykovsky on their use for the preparation of strained rings. More recently, the chemistry of these compounds has experienced important growth, in part due to the similarity of their reactivities with diazo compounds. This short review provides an overview on the great assortment of reactions of sulfoxonium ylides, outlining a comparison between the chemistry of these ylides and their congeners: sulfonium ylides and diazo compounds. Insertion reactions, cyclisation reactions and ring-opening reactions are highlighted, giving particular attention to catalytic asymmetric methodologies.

中文翻译：

磺鎓叶立德：具有变色龙反应性的简单化合物

1930 年首次公开的硫叶立德在 1960 年代开始受到更多关注，这主要归功于 Corey 和 Chaykovsky 对它们用于制备应变环的研究。最近，这些化合物的化学性质经历了重要的发展，部分原因是它们与重氮化合物的反应性相似。这篇简短的综述概述了锍叶立德的各种反应，概述了这些叶立德及其同系物的化学性质：锍叶立德和重氮化合物。突出显示插入反应、环化反应和开环反应，特别关注催化不对称方法。

更新日期：2020-11-03

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