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Recent Advances and Applications of tert-Butyl Nitrite (TBN) in Organic Synthesis
Mini-Reviews in Organic Chemistry ( IF 1.9 ) Pub Date : 2020-01-31 , DOI: 10.2174/1570193x15666181029141019
Nader Ghaffari Khaligh 1
Affiliation  

This mini-review will present the recent applications of Tert-Butyl Nitrite (TBN) in organic synthesis. Due to its unique structural feature and wide application, TBN holds a prominent and great potential in organic synthesis. The applications of TBN in three areas viz. aerobic oxidation, annulation, and diazotization were reviewed recently; now, the current mini-review will describe the studies carried out to date in areas such as nitration of alkane, alkene, alkyne, and aromatic compounds, nitrosylation and sequential nitrosylation reactions, using TBN as source of oxygen and nitrogen. The mechanisms of these transformations will be briefly described in this mini-review.



中文翻译:

亚硝酸叔丁酯(TBN)在有机合成中的最新进展和应用

这份小型回顾将介绍亚硝酸叔丁酯(TBN)在有机合成中的最新应用。由于其独特的结构特征和广泛的应用,TBN在有机合成中具有突出的巨大潜力。TBN在三个领域的应用。最近对有氧氧化,正电子化和重氮化进行了综述;现在,当前的小型综述将描述迄今为止在以下领域进行的研究:烷烃,烯烃,炔烃和芳族化合物的硝化,亚硝化和顺序亚硝化反应,并使用TBN作为氧和氮的来源。这些转换的机制将在本微型评论中简要介绍。

更新日期:2020-01-31
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