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2-(4-{[4-Methyl-6-(1-methyl-1H-1,3-benzodiazol-2-yl)-2-propyl-1H-1,3-benzodiazol-1-yl] methyl} phenyl) benzoic acid as green corrosion inhibitor for mild steel in 1 M hydrochloric acid
Ain Shams Engineering Journal ( IF 6.0 ) Pub Date : 2016-07-30 , DOI: 10.1016/j.asej.2016.07.003
Chandrabhan Verma , M.A. Quraishi , Neeraj Kumar Gupta

Present study describes the inhibition property of benzo 1,3-diazol 2-(4-{[4-Methyl-6-(1-methyl-1H-1,3-benzodiazol-2-yl)-2-propyl-1H-1,3-benzodiazol-1-yl] methyl} phenyl) benzoic acid (Telmisartan, Cresar-H) on mild steel corrosion in 1 M HCl using weight loss, electrochemical, and surface measurements. Results showed that the corrosion inhibition efficiency (η%) increases with increasing Telmisartan concentration and attained the maximum value of 97.39% at 125 mg L−1 concentration. Polarization studies revealed that Telmisartan acted as cathodic type inhibitor. Electrochemical impedance spectroscopy (EIS) studies suggested that the Telmisartan inhibits mild steel corrosion by becoming adsorbate at the metallic/electrolyte surfaces. Among the several tested isotherms, adsorption of the Telmisartan on mild steel surface obeyed the Temkin adsorption isotherm. The values of the apparent activation energy (Ea) suggested that Telmisartan inhibited metallic corrosion by creating energy barrier for corrosion process. The adsorption of corrosion inhibition was well supported by SEM/EDX and AFM studies.



中文翻译:

2-(4-{[4-甲基-6-(1-甲基-1 H -1,3-苯并二唑-2-基)-2-丙基-1 H -1,3-苯并二唑-1-基]甲基}苯基)苯甲酸在1 M盐酸中作为低碳钢的绿色缓蚀剂

本研究描述了苯并1,3-二唑2-(4-{[4-甲基-6-(1-甲基-1 H -1,3-苯并二唑-2-基)-2-丙基-1]的抑制性质H -1,3-苯并二唑-1-基]甲基}苯基)苯甲酸(替米沙坦(Telmisartan,Cresar-H))在1 M HCl中的轻钢腐蚀下,采用失重,电化学和表面测量。结果表明,随着替米沙坦浓度的增加,缓蚀效率(η%)增加,在125 mg L -1时达到最大值97.39%。浓度。极化研究表明替米沙坦起着阴极型抑制剂的作用。电化学阻抗谱(EIS)研究表明,替米沙坦通过在金属/电解质表面吸附而抑制轻钢腐蚀。在几种测试的等温线中,替米沙坦在低碳钢表面的吸附符合Temkin吸附等温线。表观活化能(E a)的值表明替米沙坦通过为腐蚀过程创建能垒来抑制金属腐蚀。SEM / EDX和AFM研究很好地支持了缓蚀剂的吸附。

更新日期:2016-07-30
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