The development of fluorescent smart materials by introducing white light emission into supramolecular polymer hydrogels, and tuning their aggregation-induced emission (AIE) effect are essential for the manufacture of advanced functional materials. Herein, a novel bi-component supramolecular polymer hydrogel (NDG) was successfully constructed via a simple host-guest assembly process based on two easy-to-synthesize tripodal gelators (NTS and DTB). Strikingly, the NDG exhibits strong white aggregation-induced emission (WAIE), and can act as an AIE-based sensor for ultrasensitive detect Fe³⁺ and F^-. The lowest limits of detection (LODs) are 5.33 × 10^-9 M and 1.61 × 10^-8 M, respectively. The xerogel of NDG exhibits nice adsorption and separation capacity for Fe³⁺, the adsorption rate reachs to 99.26%. In addition, the prepared NDG-based thin films can be used as rewritable fluorescent display material for the continuity detection of Fe³⁺ and F^-. Due to the outstanding optical behavior of the NDG, it also be used as an “IMPLICATION” logic gate at the molecular level. The AIE hydrogel-guided enriches the self-assembly strategy of new supramolecular polymers, which also makes it become a good candidate for flexible optical materials.

通过将白光发射引入超分子聚合物水凝胶并调节其聚集诱导发射（AIE）效果来开发荧光智能材料，对于制造高级功能材料至关重要。本文中，基于两个易于合成的三脚架凝胶器（NTS和DTB），通过简单的宿主-客体组装过程成功地构建了新型双组分超分子聚合物水凝胶（NDG）。引人注目的是，NDG显示出强白聚集诱导的发射（WAIE），和作为基于AIE-传感器，用于超灵敏检测的Fe可以充当³⁺和F ^- 。最低检测限（LOD）为5.33×10 ^-9M和1.61×10 ^-8M。NDG的干凝胶对Fe ³⁺具有良好的吸附和分离能力，吸附率达到99.26％。此外，所制备的NDG为基础的薄膜可以用作可重写荧光显示材料用于连续性检测的Fe ³⁺和F ^- 。由于NDG出色的光学性能，它在分子水平上也可用作“ IMPLICATION”逻辑门。AIE水凝胶引导丰富了新型超分子聚合物的自组装策略，这也使其成为柔性光学材料的理想选择。