Electrochemical Oxidation‐induced Difunctionalization of Alkynes and Alkenes with Sulfonyl Hydrazides: Facile Access to β‐Selenovinyl Sulfones and β‐Ketosulfones,Asian Journal of Organic Chemistry

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Electrochemical Oxidation‐induced Difunctionalization of Alkynes and Alkenes with Sulfonyl Hydrazides: Facile Access to β‐Selenovinyl Sulfones and β‐Ketosulfones
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-09-14 , DOI: 10.1002/ajoc.202000403
Xianqiang Kong _{1,

2} , Ke Yu ₂ , Qianjin Chen ₂ , Bo Xu ₂

Affiliation

We report here in an efficient electrochemical oxidative selenosulfonylation of alkynes and oxysulfonylation of alkenes without use of metal catalysts. This method provides a practical access to a wide range of β‐(seleno)vinyl sulfones and β‐keto sulfones. These reactions can tolerate various functional groups and be easily scaled‐up.

中文翻译：

磺酰肼用电化学氧化法诱导炔烃和烯烃的双官能化：轻松获得β-硒代新戊基砜和β-酮砜

我们在不使用金属催化剂的情况下，在炔烃的有效电化学氧化硒代磺化反应和烯烃的氧磺酰化反应中进行了报道。这种方法为广泛使用β-（硒代）乙烯基砜和β-酮砜提供了一种实用途径。这些反应可以耐受各种官能团，并且易于扩大规模。

更新日期：2020-11-17

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