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Crystal Structure of a Commercial Product CalledLead Cyanurate
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2015-03-20 , DOI: 10.1002/zaac.201500103 Konstantin Dolabdjian , Markus Ströbele , H.-Jürgen Meyer
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2015-03-20 , DOI: 10.1002/zaac.201500103 Konstantin Dolabdjian , Markus Ströbele , H.-Jürgen Meyer
The reaction of PbO with cyanuric acid was reported to give lead cyanurate, described in the literature as Pb3(O3C3N3)2·2H2O. Crystalline powders were prepared and investigated by X-ray powder diffraction, yielding a monoclinic crystal structure (space group Cc, a = 16.6217(1) A, b = 6.7161(1) A, c = 12.4308(1) A, β = 117.567(1)°). The structure solution and refinement yielded lead oxide isocyanurate corresponding to the formula Pb3O2(O3C3N3H2)2, with a layered arrangement of [Pb3O2]2+ ions and monovalent isocyanurate anions in an alternating fashion.
中文翻译:
称为氰尿酸铅的商业产品的晶体结构
据报道,PbO 与氰尿酸反应生成氰尿酸铅,在文献中描述为 Pb3(O3C3N3)2·2H2O。制备结晶粉末并通过 X 射线粉末衍射进行研究,得到单斜晶体结构(空间群 Cc, a = 16.6217(1) A, b = 6.7161(1) A, c = 12.4308(1) A, β = 117.567 (1)°)。结构解和精制得到氧化铅异氰脲酸酯,其分子式为 Pb3O2(O3C3N3H2)2,其中 [Pb3O2]2+ 离子和单价异氰脲酸酯阴离子以交替方式分层排列。
更新日期:2015-03-20
中文翻译:
称为氰尿酸铅的商业产品的晶体结构
据报道,PbO 与氰尿酸反应生成氰尿酸铅,在文献中描述为 Pb3(O3C3N3)2·2H2O。制备结晶粉末并通过 X 射线粉末衍射进行研究,得到单斜晶体结构(空间群 Cc, a = 16.6217(1) A, b = 6.7161(1) A, c = 12.4308(1) A, β = 117.567 (1)°)。结构解和精制得到氧化铅异氰脲酸酯,其分子式为 Pb3O2(O3C3N3H2)2,其中 [Pb3O2]2+ 离子和单价异氰脲酸酯阴离子以交替方式分层排列。