Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-09-08 , DOI: 10.1016/j.cplett.2020.137964 Luhao Kang , Jie Tang , Shuai Tang , Kun Zhang , Yukinori Hato , Yoshihiko Takeda , Lu-Chang Qin
To improve the lithium storage properties of anode in lithium ion capacitors (LICs), reduced graphene oxide (rGO) decorated with crystallized cobalt borate nanoparticles (Co-B/rGO) was prepared by an in-situ grow method. Microstructural characterizations demonstrate that crystallized Co-B nanoparticles not only act as an effective electron transfer bridge between rGO nanosheets but also provide more active sites for lithium storage. As a result, LIC based on Co-B/rGO anode exhibited stable cycling performance with a capacitance retention of 75% after 2000 cycles at 2000 mA g-1, and high energy and power density. Thus, Co-B/rGO can be a promising anode material for LICs.
中文翻译:
结晶的硼酸钴纳米粒子作为锂离子电容器中的阳极修饰的还原石墨烯氧化物。
为了提高锂离子电容器(LICs)中阳极的锂存储性能,通过原位生长方法制备了用结晶的硼酸钴纳米颗粒(Co-B / rGO)装饰的还原氧化石墨烯(rGO)。微观结构表征表明,结晶的Co-B纳米粒子不仅充当rGO纳米片之间的有效电子转移桥,而且还提供了更多的锂存储活性位。结果,基于Co-B / rGO阳极的LIC表现出稳定的循环性能,在2000 mA g -1的2000次循环后,电容保持率为75%,并且具有高能量和功率密度。因此,Co-B / rGO可以成为LIC的有希望的阳极材料。