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Transition‐Metal Phosphides: Activity Origin, Energy‐Related Electrocatalysis Applications, and Synthetic Strategies
Advanced Functional Materials ( IF 18.5 ) Pub Date : 2020-09-06 , DOI: 10.1002/adfm.202004009
Zonghua Pu 1, 2 , Tingting Liu 3, 4 , Ibrahim Saana Amiinu 2 , Ruilin Cheng 2 , Pengyan Wang 2 , Chengtian Zhang 2 , Pengxia Ji 2 , Weihua Hu 3 , Jian Liu 4 , Shichun Mu 1, 2
Affiliation  

Developing highly efficient and stable electrocatalysts plays an important role in energy‐related electrocatalysis fields. Transition‐metal phosphides (TMPs) possess a series of advantages, such as high conductivity, earth‐abundance reserves, and good physicochemical properties, therefore arousing wide attention. In this review, the electrochemical activity origin of TMPs, allowing the rational design and construction of phosphides toward various energy‐relevant reactions is first discussed. Subsequently, their unique energy‐related electrocatalysis nature toward hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), hydrogen oxidation reaction (HOR), carbon dioxide reduction reaction (CO2RR), nitrogen reduction reaction (NRR), urea oxidation reaction (UOR), methanol oxidation reaction (MOR), and others is highlighted. Then, the TMPs’ synthetic strategies are analyzed and summarized systematically. Finally, the existing key issues, countermeasures, and the future challenges of TMPs toward efficient energy‐related electrocatalysis are briefly discussed.

中文翻译:

过渡金属磷化物:活性起源,与能量有关的电催化应用和合成策略

在能源相关的电催化领域,开发高效,稳定的电催化剂起着重要作用。过渡金属磷化物(TMPs)具有一系列优势,例如高电导率,地球丰度储备和良好的理化特性,因此引起了广泛关注。在这篇综述中,首先讨论了TMPs的电化学活性起源,它允许对各种能量相关反应进行合理的磷化物设计和构建。随后,它们具有独特的与能量相关的电催化性质,分别用于放氢反应(HER),放氧反应(OER),氧还原反应(ORR),氢氧化反应(HOR)和二氧化碳还原反应(CO 2RR),氮还原反应(NRR),尿素氧化反应(UOR),甲醇氧化反应(MOR)等。然后,系统地分析和总结了TMPs的综合策略。最后,简要讨论了TMPs在高效能源相关的电催化方面存在的关键问题,对策和未来的挑战。
更新日期:2020-11-04
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