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Meta-cresol degradation by persulfate through UV/O3 synergistic activation: Contribution of free radicals and degradation pathway
Science of the Total Environment ( IF 8.2 ) Pub Date : 2020-09-06 , DOI: 10.1016/j.scitotenv.2020.142219
Luxi Zou , Yan Wang , Chou Huang , Bingbing Li , Jinze Lyu , Shuo Wang , Hui Lu , Ji Li

The kinetic and pathway of meta-cresol (m-cresol) degradation were studied by persulfate oxidation through UV/ozone activation (UV/O3–Na2S2O8) to improve m-cresol removal to eliminate ecological risks. Experimental results showed that the degradation effect of m-cresol with an initial concentration of 50 mg/L was 99.8% in 30 min under the optimization conditions. The reaction kinetic model in the UV/O3–Na2S2O8 system shows that the initial pH value, the respective ozone, and the persulfate dosage were positively correlated with the degradation rate constant value (k). The apparent degradation rate of m-cresol in the UV/O3–Na2S2O8 system was 0.2216 min−1, and the synergy factor (f) was larger than 1, thereby demonstrating a synergistic effect of UV, ozone, and persulfate. The dominant free radicals in the system were sulfate radical (SO- 4·) and hydroxyl radical (·OH), and the contribution ratio of SO- 4· to m-cresol degradation was higher than ·OH. The degradation process of m-cresol by UV/O3 − Na2S2O8 was mainly through the electrophilic addition reaction to substitute the ortho- and para-positions of the hydroxyl group on the benzene ring, followed by the ring-opening reaction and mineralization of the aliphatic compound to achieve the complete degradation of m-cresol.



中文翻译:

过硫酸盐通过UV / O 3协同活化降解间甲酚:自由基的贡献和降解途径

通过过硫酸盐通过紫外线/臭氧活化(UV / O 3 -Na 2 S 2 O 8)的过硫酸盐氧化来研究间甲酚(间甲酚)降解的动力学和途径,以改善间甲酚的去除,从而消除生态风险。实验结果表明,在优化条件下,初始浓度为50 mg / L的间甲酚在30 min内的降解率为99.8%。在UV / O 3 -Na 2 S 2 O 8系统中的反应动力学模型表明,初始pH值,相应的臭氧和过硫酸盐剂量与降解速率常数值正相关(k)。在UV / O 3 -Na 2 S 2 O 8系统中间甲酚的表观降解速率为0.2216 min -1,并且协同因子(f)大于1,从而证明了UV,臭氧,和过硫酸盐。系统中的主要自由基为硫酸根(SO-4·)和羟基(·OH),SO-4·对间甲酚降解的贡献率高于·OH。UV / O 3  -Na 2 S 2 O 8对间甲酚的降解过程 主要是通过亲电加成反应取代苯环上羟基的邻位和对位,然后进行开环反应和脂肪族化合物的矿化,以实现间甲酚的完全降解。

更新日期:2020-09-07
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